Oxygen has two unpaired electrons in its outermost shell, making it strongly paramagnetic. When placed in a non-uniform magnetic field, Oβ molecules are attracted toward the region of highest field intensity. This magnetic attraction creates a measurable mechanical force on the dumbbell system.
Two glass spheres filled with nitrogen are suspended on a taut quartz fibre in a non-uniform magnetic field. When oxygen-containing gas enters the chamber, Oβ molecules are attracted to the magnetic poles, displacing the nitrogen spheres. The rotation angle of the dumbbell is directly proportional to Oβ partial pressure.
An optical or electromagnetic feedback system measures this deflection and converts it to a 4β20 mA signal.
- High accuracy (Β±0.1% Oβ)
- Fast response (<5 seconds)
- Non-consumable sensor
- Long-term stability
- Suitable for process & safety
- No electrochemical reaction
- Sensitive to mechanical vibration
- Affected by pressure changes
- Flow rate affects accuracy
- NO and NOβ also paramagnetic (interference)
- Requires clean, dry sample gas
π§² Paramagnetic
- Magnetic principle
- No consumables
- 0β25% range
- Room temp op.
- Low maintenance
π₯ Zirconia
- Electrochemical
- Cell wears out
- ppm to %
- 700Β°C operation
- In-situ possible